@Article{PoliCaVaGaBaGo:2017:InVoCy,
author = "Poli, Anne Karoline dos Santos and Caetano, Gustavo Machado
Domingues and Vargas, Ludmila Resende and Gama, Adriana Medeiros
and Baldan, Maur{\'{\i}}cio Ribeiro and Gon{\c{c}}alves,
Emerson Sarmento",
affiliation = "{Instituto Tecnol{\'o}gico de Aeron{\'a}utica (ITA)} and
{Instituto de Aeron{\'a}utica e Espa{\c{c}}o (IAE)} and
{Instituto Tecnol{\'o}gico de Aeron{\'a}utica (ITA)} and
{Instituto de Aeron{\'a}utica e Espa{\c{c}}o (IAE)} and
{Instituto Nacional de Pesquisas Espaciais (INPE)} and {Instituto
Tecnol{\'o}gico de Aeron{\'a}utica (ITA)}",
title = "Electrosynthesis of polyaniline on carbon fiber felt: influence of
voltammetric cycles on electroactivity",
journal = "Journal of the Electrochemical Society",
year = "2017",
volume = "164",
number = "9",
pages = "D631--D639",
abstract = "The carbon materials and conducting polymers are known by
application in electronic devices. This work aims to study the
initial steps parameters of polyaniline electrosynthesis on carbon
felts annealed at 1600 K by changing the number of voltammetry
cycles in aniline acid solution. The characterization was
performed by Field Emission Gun Scanning Electron Microscopy,
X-ray Diffraction, Infrared Fourier Transform Spectroscopy, Raman
Spectroscopy and Electrochemical Impedance Spectroscopy. Under
increasing number of cycles, the growth was more intense and it
was easy to observe the pores clogging. Besides, it was noticed
that emeraldine formation occurred progressively, from structures
less to more oxidized: the polyaniline less cycled resulted
closest that leucoemeraldine; polyaniline from nine cycles
resulted closest to emeraldine, but all of them showed
electroactive defects related to electrical charge (polarons) and
conductivity (bipolarons). It was also observed that prime layers
of polyaniline, formed until three cycles, followed more intense
attraction of charges in solution to layer surface. This effect
was emphasized from 3rd to 6th cycles.",
doi = "10.1149/2.1521709jes",
url = "http://dx.doi.org/10.1149/2.1521709jes",
issn = "0013-4651",
language = "en",
targetfile = "poli_electrosynthesis.pdf",
urlaccessdate = "27 abr. 2024"
}